KMID : 1059519970410040175
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Journal of the Korean Chemical Society 1997 Volume.41 No. 4 p.175 ~ p.179
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Eu3+ Luminescence in Two-Dimensional Sr2-2xEuxKxSnO4 with K2NiF4 Structure
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Yo Chul-Hyun
Chau P. T. Minh Ryu Kwang-Hyun Anh T. Kim
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Abstract
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Luminescence of Eu3+ has been studied in Sr2-2xEuxKxSnO4 with two-dimensional K2NiF4 structure. The 5D0 ¡æ 7F0 emission line of Eu3+ ion represents the J=0 ¡æ J=0 transition which is forbidden by a Judd-Ofelt selection rule for electric dipole transition in 4f shell of Eu3+ ions. However, the emission line of 5D0 ¡æ 7F0 transition gains remarkably high intensity in Eu3+ emission spectra of Sr2-2xEuxKxSnO4. The transition of 5D0 ¡æ 7F0 is allowed due to distortion of local structure around Eu3+ ions.
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KEYWORD
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